A team led by DGIST professor Seo Dae-ha has developed an experimental strategy to control and observe the chemical reaction of a single nanocatalyst using an optical microscope. The work is expected to contribute to catalyst design based on accurate understanding of the photocatalytic reaction through an analysis method that helps understanding the electron excitation phenomenon and transition path.

This technology is expected to provide an experiment strategy based on system chemistry, a new experiment strategy for precisely studying photocatalysts at the single particle level. [1]

Figure 1. Electrons moving inside gold: Optical microscope experiment strategy

Figure 1 shows plasmonic metals at the nanometer level, e.ggold, show a high rate of light absorption in a wide range of visible light. They, in combination with semiconductor photocatalysts, act as a medium to increase light absorption. An excitation occurs where electrons gain energy and move in response to the absorption of light, and it follows different paths depending on the size of the metal and the wavelength of the light. There are various hypotheses about the effect of this electron movement as a catalyst. The research team was able to test the hypotheses and discover how electrons are transferred by developing a new microscope that is experimentally simpler and more sophisticated than the usual method of observing chemical reactions. [2]

Professor Seo Dae-ha's research team developed hybrid nanoparticles, and lasers of different wavelengths were combined into a new form, respectively, to investigate the reaction between them to test various hypotheses on the electron excitation phenomenon through experiments and verify them one by one. Through this process, the team was able to selectively induce electron excitation in gold nanoparticles, and quantitatively analyze their contributions by evaluating the increase in the reactivity of the catalyst. In addition, the team confirmed that these excited electrons were transferred to the semiconductor to increase stability and reactivity at the same time. [3]

“The observational technology reported here is a technology that observes chemical reactions with high precision, efficiency, and low cost,” said Professor Seo Dae-ha of the Department of Physics and Chemistry at DGIST, while adding that “it is expected that it will contribute to the sophisticated design of catalysts and will be applied as a sophisticated evaluation and control technology using nanoparticles for pharmaceuticals.” [4]

References:

1. https://phys.org/news/2022-08-optical-microscope-strategy-electrons-gold.html
2. https://newsliveflorida.com/the-optical-microscope-strategy-allows-observers-to-check-the-electrons-moving-inside-the-gold/28162/
3. https://www.sciencedaily.com/releases/2022/08/220812113456.htm
4. https://mixpoint.in/analytical-chemistry-materials-science/2022/08/optical-microscope-strategy-allows-observers-to-check-electrons-moving-inside-gold/

Cite this article:

Thanusri swetha J (2022), Electrons moving inside gold: Optical microscope experiment strategy, Anatechmaz, pp. 393